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DOI: 10.1126/science.1224757
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AppliedSciences,Vol.351(KluwerAcademicPublishers,8.G.Akovali,C.A.Bernardo,J.Leidner,L.A.Utracki,13.Newpolymeroffersclosedlooprecyclingtoautomotive
Dordrecht,Netherlands,1998),chap.1.
M.Xanthos,Eds.,FrontiersintheScienceandTechnologyindustry,WasteManagementWorld,12April2012,2.U.S.EnvironmentalProtectionAgency,Plastics,
ofPolymerRecycling,NATOAdvancedStudyInstitutewww.waste-management-world.com/index/display/article-http://www.epa.gov/osw/conserve/materials/plastics.htm.Series,SeriesE:AppliedSciences,Vol.351(Kluwerdisplay/2121000211/articles/waste-management-world/3.PackagingLaw.com,USrecyclingratesforplasticsbottlesupAcademicPublishers,Dordrecht,Netherlands,1998),recycling/2012/04/New_Polymer_Offers_Closed_Loop_in2010,www.packaginglaw.com/3232_.shtml.
chaps.2and3.
Recycling_to_Automotive_Industry.html.
4.
A.L.Bisio,M.Xanthos,Eds.,HowtoManagePlastics9.S.Strom,Rethinkingrecycling,NewYorkTimes,24March14.Buildingtalk.com,Axioninvestigatescarpetrecycling
Waste:TechnologyandMarketOpportunities2012,p.B1.
options,15January2010,http://www.buildingtalk.com/(CarlHanserVerlag,Munich,NewYork,1994),10.J.Berry,Plastic#5recyclinggotyoufeelingblue?,
building-industry-news-/sustainability-and-energy-chap.10.
http://earth911.com/news/2009/02/03/plastic-5-efficiency-/axion-investigates-carpet-recycling-options/5.M.B.Priebe,Ecolife,www.ecolife.com/recycling/plastic/recycling-got-you-feeling-blue.
364095.article.
how-to-recycle-pp-plastic-5.html.
11.M.Chanda,S.K.Roy,PlasticsTechnologyHandbook,
15.M.Xanthos,inMixingandCompoundingofPolymers,
6.S.Straus,InformationonRM5polymerbanknote,(CRCPress,BocaRaton,FL,ed.4.,2007),sectionI.Manas-Zloczower,Ed.(CarlHanserVerlag,Munich,http://www.polymernotes.org.
6-31.
ed.2,2009),chap.20,pp.757–766.
7.
M.Stones,Food-gradePPrecyclingmovescloser,says12.A.L.Bisio,M.Xanthos,Eds.,HowtoManagePlastics
WRAP,www.foodproductiondaily.com/Packaging/Food-Waste:TechnologyandMarketOpportunities(CarlHansergrade-PP-recycling-moves-closer-says-WRAP.Verlag,Munich,NewYork,1994),chap.13.
10.1126/science.1221806
PERSPECTIVE
taltothefeasibilityofreuseandrecyclingbecauseitdictatesthecostoffurtherprocessing.
TheChallengesofReusingMiningMiningandmineral-processingwastescon-sistofrocks,soils,oilsands,andloosesediments.andMineral-ProcessingWastes
Themineralogicalandchemicalcharacterizationsofminingwastesareusefulinforecastinggeo-technicalproperties(particlesizeandstructure,ZhengfuBian,1*XiexingMiao,2ShaogangLei,3Shen-enChen,4plasticity,bulkdensity,drydensity,shearstrength)WenfengWang,5SueStruthers6ofthewasteandtheleachabilityofpotentiallyharmfulcompounds.Themineralogicalcompo-sitionoftheprocessingwastescanbeheteroge-Miningandmineral-processingwastesareoneoftheworld’slargestchronicwasteconcerns.neousbecauseofthedepositionofwastesfromTheirreuseshouldbeincludedinfuturesustainabledevelopmentplans,butthepotentialtheprocessingofdifferentminesources,yieldingimpactsonanumberofenvironmentalprocessesarehighlyvariableandmustbethoroughlyarangeofphysicalandchemicalproperties.Forassessed.Thechemicalcompositionandgeotechnicalpropertiesofthesourcerockdetermineexample,themineralcompositionoftailingsfromwhichusesaremostappropriateandwhetherreuseiseconomicallyfeasible.Ifproperlyevaluated,metalandnonmetalminesinChinaisdividedminingwastecanbereusedtoreextractminerals,provideadditionalfuelforpowerplants,intoeightbroadtypes(7).
supplyconstructionmaterials,andrepairsurfaceandsubsurfacelandstructuresalteredbyminingThemostimportantmineralogicalconsidera-activitiesthemselves.
tionsarethosethatinfluencemineralrecovery,M
decontamination,acidrockdrainage,andpro-iningandmineral-processingwastes—(3).Forexample,NorthAmericaproducesmorecessesthataffectsedimentstrengthandcohesion.thesolidandliquidmaterialsgener-than10timesasmuchsolidminewasteasmu-Theconcentrationsoftoxicelementsandmetal-atedafterminingandoreprocessingat
nicipalsolidwastepercapita(4).Becausemin-loidssuchasCd,As,Hg,Cr,andPbarehighlyornearminesites(1)—havenocurrenteconomiceralproductioncontinuestobenecessaryforvariable,butifpresentinsufficientquantities,use.Anumberofenvironmentalproblemsareas-economicdevelopment,therecyclingandreusetheymayinhibitplantgrowthordegradewatersociatedwiththedisposalofthiswaste,includ-ofminingandmineral-processingwastesarequality(8,9).Methodssuchasmechanicalsep-ingcontaminationofstreamsandlakes(2)andimportantmanagementstrategiesnowandinthearation,chemicalcarbonation,andhydrothermalpronouncedlandscapetransformation(e.g.,stock-future(5).
mineralization(10)canremovesomeofthesepiledwasterockandtailings,subsidencebasins,Theoriginofminingandmineral-processingtoxicelements,butmayalsoinsomecasesmo-openpits,andremovalofoverburdenrockandwastesiscloselyrelatedtotheformationofthebilizemetalsingroundwaterandsurfacewaterstopsoil)(Fig.1).Despiteseveraleffortstoreducetargetresourceorminerals.Forexample,manythroughoxidation.
theamountofwasteproduced,solidmineralwastescoaldepositsexistinsubsidedregionsresultingThereuseofminingandmineral-processingremainoneoftheworld’slargestwastestreams
frommountainformation;hence,theoverlaysofwastesmayminimizetheenvironmentalimpactscoalresourcesaregenerallynotverythickandrelatedtodisposal;however,somereuseandre-consistofrelativelyinactivesedimentaryrocks.cyclingmeasuresmayactuallycausenewand1InstituteforLandResources,ChinaUniversityofMiningandIn2010,worldwidetotalcoalproductionwasseriousenvironmentalproblems.Theoverallenvi-Technology,Xuzhou,JiangsuProvince221116,China.2StateKeyabout7273.3milliontonnes(Mt),withanesti-ronmentalcostscanbedeterminedbyvariousap-LaboratoryforGeomechanicsandDeepUndergroundEngineer-ing,ChinaUniversityofMiningandTechnology,Xuzhou,Jiangsumatedwasteofabout1454.7Mtduetocoalpro-proachessuchasecologicalriskassessment,lifeProvince221116,China.3JiangsuKeyLaboratoryforResourcesduction(6).Ofthiswaste,upto100%(totalwastecycleassessment,sustainabilityoperationsassess-andEnvironmentalInformationEngineering,ChinaUniversitywithnoproductionofprospectiveminerals)ment,andecologicalfootprintestimates(3,11,12).ofMining4andTechnology,Xuzhou,JiangsuProvince221116,maybeduetotheminingorextractionmethod.Economiccost-benefitanalysis,however,istheChina.DepartmentofCivil&EnvironmentalEngineering,Uni-versityofNorthCarolina,Charlotte,NC28223,USA.5SchoolofWastesproducedduringcoalpreparation(remov-ultimatedriverintermsofthefeasibilityofaspe-ResourceandEarthScience,ChinaUniversityofMiningandalofundesiredmaterialsfromcoalthroughcoalcificreusetechnology.IfthecostsoffinaltargetTechnology,Xuzhou,JiangsuProvince221116,China.6Skapawashing,crushing,screening,anddewatering)materialextractionorminewastereusemethodareMiningServicesLtd.,Hillbanks,Burray,OrkneyKW172SX,UK.mayreach10to30%ofrawcoal;mostoftheseeconomicallyprohibitive,theneventhemosteco-*Towhomcorrespondenceshouldbeaddressed.E-mail:wastesareinslurryformasaresultofthewashingfriendlyprocessmethodswillbedifficulttoimple-zfbian@cumt.edu.cn
process.Thefinalformofwastecanbedetrimen-mentwithoutregulationorgovernmentsubsidies.
70210AUGUST2012VOL337
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Oneapproachtominimizecostistoimprovewastepro-cessingefficiency,whichde-pendsontheoptimizationoftheresourceallocationtomin-Crushing
imizeenvironmentaleffectsSurface mining
Grindingwhilemaximizingthequantity
Overburden,
ofwastesprocessedandtheopen-pit stopeOre separationTailingsassociatedbenefits.Avoiding
Ore processingwasteinthefirstplaceistheWaste waterConcentrationWaste rock
Land subsidencedewateringmostfavoredmeansofincreasing
wasteprocessingefficiencybe-Ore concentratefor further processingcauseithastheleastenviron-mentalimpactandpossiblyRock fractures
Underground mininginvolvestheleastenergyspent
onwastedisposal;however,itisalsothemostdifficulttoaccomplish.TheuseofsolidCollapsed rock filling the mined areaminingwasteasbackfillandstabilizationmaterialinunder-groundcoalminingispoten-tiallyagoodwaytoincreaseFig.1.Wastegeneratedandenvironmentaleffectsduringdifferentminingstages.efficiency,butthetrade-offisnotstraightforwardbecauseof
7.J.R.Zhang,W.Z.Wang,F.P.Li,A.D.Wang,theenergycostsrelatedtoadditionaltunnelop-practiceinChinabutnotintheUnitedStates.
ComprehensiveUtilizationandResourcesofMetalMineerationstomovethematerial,aswellastheneedWasterockandtailingshavealsobeenusedas
Tailings(MetallurgicalIndustryPress,Beijing,2002).
tocreateopenspacefortemporarywastestor-auxiliarysourcematerialsforproducingbuild-8.M.A.Armientaetal.,Appl.Geochem.(2012).
ingmaterialssuchascement,hollowbricks,ageandmanagement(13).9.G.Geise,E.LeGalley,M.S.Krekeler,Environ.EarthSci.
Residualminingwastesafterreuseorre-concrete,andglass(17,19–21).Groundsub-62,185(2011).10.G.T.Goodman,M.J.Chadwick,Eds.,sourcerecoveryaretypicallydiscardedatspe-sidencebasinsinducedbymininghavealso
EnvironmentalManagementofMineralWastescificsitessuchastailingponds.Ifwastesarebeenfilledwithwasterockandcoveredwith
(Sijthoff&Noordhoff,AlphenaandenRijn,Netherlands,
notdisposedofproperly,wastewaters,especial-topsoil.Therepairedlandcanthenbereclaimed1978).lyfromhydrocarbonwastes,canenterstreamsasfarmland,grassland,orconstructionland(11).11.Z.Bian,D.Jin,J.Dong,S.Mu,J.MiningSafetyEng.24,
132(2007).andpotablesupplywells.TheprimarygoalforThewasterockortailingscanalsobecrushed
12.A.Golev,G.D.Corder,Miner.Eng.29,58(2012).disposalofminingandmineral-processingwastesandmixedwithflyashandcementasbackfillin
13.X.Miao,J.Zhang,G.Guo,MethodandTechnologyofshouldbetoensurethatthewasteremainsphys-minedcavities,whichhasthepotentialtoreduce
Fully-MechanizedCoalMiningwithSolidWasteFilling
ically,geographically,chemically,andradio-surfacesubsidenceandisapromisingmethodfor(ChinaUniv.ofMiningandTechnologyPress,Xuzhou,logicallystableandinert,andifthisisnotlargeamountsofwastereuse(22).China,2010).
14.D.M.Franks,D.V.Boger,C.M.Côte,D.R.Mulligan,possible,thewastesmustbeisolatedandpre-Itisdifficulttoassignauniversalmethodto
Resour.Policy36,114(2011).ventedfrominteractingwiththeecosystemreuseallkindsofminingandmineral-processing
15.M.L.Smith,R.E.Williams,Eng.Geol.43,11
(14).Reuseofdiscardedminewaste,referredwastes.Eachkindofwastehasitsownappro-(1996).
toastailingrecovery,helpsreduceexposurepriatewaysforreuse,whichevencanvary16.H.Liu,Z.Liu,Resour.Conserv.Recycling54,1331ofwastetotheenvironmentandinsomecasesaccordingtolocalenvironmentalconditions(e.g.,(2010).
17.ASTM,StandardSpecificationforSteelSlagAggregatescanmaximizetargetmineralefficiency(15).proximitytodrinkingwater,depthofminingac-forBituminousPavingMixtures,D5106-08Forexample,wasterockorcoalslimegener-tivity).Inanysituationwhereminingandmineral-(2008).
atedafterwashingprocessesmaycontaincar-processingwastesarereintroducedbacktothe
18.K.M.Skarżyńska,WasteManag.15,83(1995).
bonwithcalorificvaluesof3350to6280kJ/kg,subsurface,effortsmustbemadetoensurethat19.Y.Chen,Y.Zhang,T.Chen,Y.Zhao,S.Bao,Construct.whichcanberemixedwithcoalforadditionalnopollutantstransferfromminingwastestoBuild.Mater.25,2107(2011).
20.M.Frías,M.I.SanchezdeRojas,R.García,powergeneration(16).Asabove,thereuseoffoodorwatersupplies.Appropriateenviron-A.J.Valdés,C.Medina,CementConcr.Compos.34,minetailingsorcoalslimesalsomayhavepo-mentalmonitoringandassessmentstudiesshould
678(2012).
tentialnegativeenvironmentalimpacts,suchasalwaysbeincludedinthereusedesign.
21.J.J.M.Heynen,H.N.J.A.Bolk,G.J.Senden,
increasedemissionsofnitrogendioxideandsul-P.J.Tummers,inWasteMaterialsinConstruction,
furdioxide.J.J.J.M.Goumans,H.A.vanderSloot,
T.G.Aalbers,Eds.(Elsevier,Amsterdam,1994),Consideringthefactorsthatdictatewhen
ReferencesandNotespp.655–664.andwhereminingwastereusemakessense
1.K.A.Hudson-Edwards,H.E.Jamieson,B.G.Lottermoser,22.X.Miao,J.Zhang,M.Feng,J.ChinaUniv.Mining
environmentally,economically,orboth,thereElements7,375(2011).Technol.18,479(2008).areseveralexamplesofsuccessfulreuseproj-2.M.A.Palmeretal.,Science327,148(2010).
Acknowledgments:SupportedbyNaturalScientificFundofects.Wasterocksandiron/steelslagshave3.L.Tiruta-Barna,E.Benetto,Y.Perrodin,Resour.Conserv.
Chinagrant50574095,ProgramforChangjiangScholarsandRecyc.50,351(2007).beenusedasalternativeaggregatesforthe
InnovativeResearchTeaminUniversitygrantIRT0865,and4.H.E.Jamieson,Elements7,381(2011).constructionofroadsandrailroadbanks(17),111ProjectgrantB07028.5.B.G.Lottermoser,Elements7,405(2011).
riverembankments,dikes,anddams(18).Asa6.“StatisticalReviewofWorldEnergy2011,”BPReportresultofregulatorypolicies,minewastereuse(2011);www.bp.com/sectionbodycopy.do?categoryId=forroadwaysandparkingareasisanaccepted3311&contentId=7066754#.10.1126/science.1224757
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