专利名称:Method for the production of optically
active enamines or the correspondingaldehydes
发明人:HEISER, BERND, DR.,STOLLER, HANSJORG,
DR.
申请号:EP87111487.2申请日:19870808公开号:EP0257411A3公开日:19890322
摘要:it is the production of chiral enaminen of general formula and the
corresponding aldehydes is described, wherein the sub\stituenten r, r\¹ andr\² in the description of the ange\gebenen meanings. this production is carriedout by isomerisation of e or z - form present as the general formula with a rhodiumdiphosphinkomplex under addition of a achiralen triarylphosphins and
gew\ünschtenfalls hydrolysis of the compound obtained the formula i to thecorresponding aldehyde.
申请人:F. HOFFMANN-LA ROCHE & CO. AKTIENGESELLSCHAFT
地址:Postfach 3255 4002 Basel CH
国籍:CH
代理机构:Cottong, Norbert A.
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